| J | Date | Locaux | Score | Visiteurs | MT | Spect | >2.5 | MT | Re | Note | Arb. | |
| 10 | 31/10/2007 | Atlético Madrid | 4 - 3 | FC Sevilla | 2-2 | 50 000 | Oui | N | 1 | 0 | 0 | |
| 10 | 31/10/2007 | Betis Sevilla | 0 - 3 | Osasuna | 0-1 | 35 000 | Oui | 2 | 2 | 0 | 0 | |
| 10 | 31/10/2007 | Deportivo | 1 - 1 | Real Mallorca | 1-1 | 10 000 | Non | N | N | 0 | 0 | |
| 10 | 31/10/2007 | Getafe CF | 2 - 0 | Athletic Bilbao | 2-0 | 8 000 | Non | 1 | 1 | 0 | 0 | |
| 10 | 31/10/2007 | Recreativo | 0 - 0 | Racing | 0-0 | 16 000 | Non | N | N | 0 | 0 | |
| 10 | 31/10/2007 | UD Almería | 0 - 1 | Real Zaragoza | 0-0 | 13 964 | Non | N | 2 | 0 | 0 | |
| 10 | 31/10/2007 | Valencia CF | 1 - 5 | Real Madrid | 0-4 | 49 500 | Oui | 2 | 2 | 0 | 0 | |
| 10 | 31/10/2007 | Villarreal CF | 3 - 0 | Levante UD | 3-0 | 14 000 | Oui | 1 | 1 | 0 | 0 | |
| 10 | 01/11/2007 | Espanyol | 0 - 0 | Real Murcia | 0-0 | 11 150 | Non | N | N | 0 | 0 | |
| 10 | 01/11/2007 | Real Valladolid | 1 - 1 | Barcelona | 1-1 | 26 000 | Non | N | N | 0 | 0 |
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