| J | Date | Locaux | Score | Visiteurs | MT | Spect | >2.5 | MT | Re | Note | Arb. | |
| 25 | 23/02/2008 | FC Sevilla | 5 - 0 | Real Zaragoza | 3-0 | 40 000 | Oui | 1 | 1 | 0 | 0 | |
| 25 | 23/02/2008 | Valencia CF | 1 - 1 | Recreativo | 1-0 | 38 000 | Non | 1 | N | 0 | 0 | |
| 25 | 24/02/2008 | Athletic Bilbao | 1 - 2 | Villarreal CF | 1-0 | 35 000 | Oui | 1 | 2 | 0 | 0 | |
| 25 | 24/02/2008 | Barcelona | 5 - 1 | Levante UD | 2-1 | 71 979 | Oui | 1 | 1 | 0 | 0 | |
| 25 | 24/02/2008 | Deportivo | 2 - 0 | Espanyol | 2-0 | 11 000 | Non | 1 | 1 | 0 | 0 | |
| 25 | 24/02/2008 | Osasuna | 3 - 1 | Atlético Madrid | 2-1 | 17 000 | Oui | 1 | 1 | 0 | 0 | |
| 25 | 24/02/2008 | Racing | 1 - 0 | UD Almería | 0-0 | 18 000 | Non | N | 1 | 0 | 0 | |
| 25 | 24/02/2008 | Real Madrid | 0 - 1 | Getafe CF | 0-0 | 73 000 | Non | N | 2 | 0 | 0 | |
| 25 | 24/02/2008 | Real Mallorca | 1 - 1 | Betis Sevilla | 0-0 | 16 000 | Non | N | N | 0 | 0 | |
| 25 | 24/02/2008 | Real Murcia | 0 - 1 | Real Valladolid | 0-1 | 18 334 | Non | 2 | 2 | 0 | 0 |
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