| J | Date | Locaux | Score | Visiteurs | MT | Spect | >2.5 | MT | Re | Note | Arb. | |
| 3 | 15/09/2007 | Athletic Bilbao | 1 - 1 | Real Zaragoza | 1-1 | 40 000 | Non | N | N | 0 | 0 | |
| 3 | 15/09/2007 | Real Madrid | 3 - 1 | UD Almería | 1-0 | 73 000 | Oui | 1 | 1 | 0 | 0 | |
| 3 | 15/09/2007 | Valencia CF | 2 - 1 | Real Valladolid | 1-1 | 40 000 | Oui | N | 1 | 0 | 0 | |
| 3 | 16/09/2007 | Deportivo | 1 - 0 | Betis Sevilla | 1-0 | 10 000 | Non | 1 | 1 | 0 | 0 | |
| 3 | 16/09/2007 | Espanyol | 1 - 0 | Getafe CF | 0-0 | 18 750 | Non | N | 1 | 0 | 0 | |
| 3 | 16/09/2007 | FC Sevilla | 4 - 1 | Recreativo | 2-0 | 45 000 | Oui | 1 | 1 | 0 | 0 | |
| 3 | 16/09/2007 | Osasuna | 0 - 0 | Barcelona | 0-0 | 19 000 | Non | N | N | 0 | 0 | |
| 3 | 16/09/2007 | Racing | 1 - 0 | Levante UD | 1-0 | 15 323 | Non | 1 | 1 | 0 | 0 | |
| 3 | 16/09/2007 | Real Mallorca | 0 - 1 | Villarreal CF | 0-0 | 17 000 | Non | N | 2 | 0 | 0 | |
| 3 | 16/09/2007 | Real Murcia | 1 - 1 | Atlético Madrid | 0-1 | 31 000 | Non | 2 | N | 0 | 0 |
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